不同年代的纸颜料的拉曼光谱和荧光光谱分析

本文研究了不同年代的纸(记事本(1921年),信纸(1934年),英语字典封面(2001年)以及标签纸(2008年))上红色颜料的显微激光拉曼光谱和荧光光谱。结果表明:不同年代的纸的颜料结构和光学性能也不同,其生产工艺也不一样。     

基于功能不可加系统的系统优化

为了揭示系统的某一功能达到最优与其所有子系统为实现系统这一功能而提供的功能之间的关系,基于系统功能具有可加和不可加的特性,探讨了功能不可加系统的功能优化方法,以子系统功能的实现度为决策变量,以系统功能发挥最大效用为目标函数,以实现功能所需的资源为约束条件,建立了功能不可加系统优化的规划模型,最后辅以算例,并通过EXCEL Solver求解进行了分析.     

Generalized saddle point theorem and asymptotically linear problems with periodic potential

We prove a critical point theorem, which is an infinite dimensional generalization of the classical saddle point theorem of P. H. Rabinowitz. As an application we obtain solution of asymptotically linear Schrödinger equations with periodic potential.     

$c$-半层空间与几乎完全正则空间一点注记

In this paper, we give some characterizations of almost completely regular spaces and c-semistratifiable spaces(CSS) by semi-continuous functions. We mainly show that:(1)Let X be a space. Then the following statements are equivalent:(i) X is almost completely regular.(ii) Every two disjoint subsets of X, one of which is compact and the other is regular closed, are completely separated.(iii) If g, h : X → I, g is compact-like, h is normal lower semicontinuous, and g ≤ h, then there exists a continuous function f : X → I such that g ≤ f ≤ h;and(2) Let X be a space. Then the following statements are equivalent:(a) X is CSS;(b) There is an operator U assigning to a decreasing sequence of compact sets(Fj)j∈N,a decreasing sequence of open sets(U(n,(Fj)))n∈N such that(b1) Fn■U(n,(Fj)) for each n ∈ N;(b2)∩n∈NU(n,(Fj)) =∩n∈NFn;(b3) Given two decreasing sequences of compact sets(Fj)j∈N and(Ej)j∈N such that Fn■Enfor each n ∈ N, then U(n,(Fj))■U(n,(Ej)) for each n ∈ N;(c) There is an operator Φ : LCL(X, I) → USC(X, I) such that, for any h ∈ LCL(X, I),0 Φ(h) h, and 0 Φ(h)(x) h(x) whenever h(x) 0.     

A tunable green alkaline-earth silicon-oxynitride solid solution (Ca1? x Sr x )Si2O2N2:Eu2+ and its application in LED

A series of (Ca_1−x−y Sr _x )Si₂O₂N₂:yEu²⁺ (x=0.0–0.97, y=0.03) phosphors were synthesized by high-temperature solid-state reaction. The XRD patterns confirm the formation of a solid solution of (Ca_1−x−y Sr _x )Si₂O₂N₂:yEu²⁺. An intense tunable green light is observed with the increasing ratio of Sr/Ca. With an increase in x, the excitation and emission spectra show a redshift and blueshift, respectively, due to large centroid shift and small Stokes shift. The temperature dependent luminescence is also investigated in the temperature range of 77–450 K. The Huang–Rhys factor and the thermal-quenching temperature are determined. Intense green LEDs were successfully fabricated based on the (Ca_1−x−y Sr _x )Si₂O₂N₂:yEu²⁺ phosphor and near-ultraviolet (∼395 nm) GaN/blue (460 nm) InGaN chips. All the results indicate that the solid solution (Ca_1−x−y Sr _x )Si₂O₂N₂:yEu²⁺ is a promising phosphor applicable to near-UV and blue LEDs for solid-state lighting.     

关于A3中仿射Weingarten曲面的一个结果

关于A³中曲面的H-定理和K-定理是众所周知的了. 该文在此基础上对Weingarten曲面作进一步的研究,得到一个更为广泛的定理.     

序半群的正则同余类

本文的目的是给出一个序半群的子集能成为某个正则同余的同余类的刻面,同时我们可以容易看出[5]中的关于一般半群(没有序关系)的相应的结论仅是本文的结论的应用.     

存货质押融资中考虑银行Downside-risk的回购契约设计

本文研究供应链金融中存货质押融资模式下回购契约的设计问题,即在需求不确定和银行下侧风险(Downside-risk)规避的前提下,通过对契约合同中变量范围的控制实现供应链的协调。文中首先给出了考虑银行利息与风险规避在内的供应链契约模型,然后分别分析了银行下侧风险控制模型下供应商的促销成本分担比例的下限值和在不减少供应商期望收益原则下该比例的上限值,最终得出该下限值由银行下侧风险控制指标和质押量共同决定,而当销售商的订购量越多时,供应商愿意接受的努力成本分担比例上限值也越大,并给出相应的上下限值。     

Development of XIAP Antagonists Based On De Novo 8,5-Fused Bicyclic Lactams

In order to develop original water soluble antagonists of X-linked inhibitor of apoptosis protein (XIAP), a novel bicyclic scaffold was designed based on 8,5-fused bicyclic lactam. During its preparation, a spontaneous rearrangement from 8,5- to 7,5-fused bicyclic lactam was observed and confirmed by MS and NMR analyses, in particular the HMBC spectra. DFT calculations were performed to understand the corresponding mechanism. It was finally prevented through changing the reaction order in the synthesis route and a Smac mimetic with this core structure, ZJ-1 was successfully obtained. The structure of this new bicyclic scaffold was well confirmed by HRMS and NMR (¹H, ¹³C, NOESY) analyses. ZJ-1 presented in addition a binding affinity to XIAP-BIR3, nearly 6 times better than that of AVPI, similar to the reported SM-128 in an in vitro fluorescence polarization (FP) assay. This preliminary result suggests that this new bicyclic scaffold could be very attractive in the development of novel anticancer agents targeting XIAP.     

射频溅射功率对Mn-Co-Ni-O薄膜结构与性能的影响

采用射频磁控溅射技术在硅衬底上制备了锰钴镍氧(Mn-Co-Ni-O, MCNO)薄膜并进行了后退火处理。利用X射线衍射、扫描电子显微镜、光学测试仪器等测试手段对晶体结构、表面形貌及光学性能进行表征。分析了不同射频溅射功率(60~100 W)对MCNO薄膜表面微观形貌、晶体结构和光学性能的影响。结果表明,在60~90 W下获得的薄膜表面致密且均匀,但在100 W下获得的MCNO薄膜表面晶粒尺寸显著增大。物相分析表明,采用射频磁控溅射沉积的MCNO薄膜主要为尖晶石结构,溅射功率对薄膜结晶质量和择优取向具有显著影响,在80 W下获得的MCNO薄膜结晶质量最佳。同时,拉曼光谱测试也表明该MCNO薄膜表现出最强的Mn⁴⁺—O对称弯曲振动和最小的压应力。紫外-可见-近红外光谱分析表明,MCNO薄膜的吸光范围主要在可见光-近红外波段,在80~90 W溅射功率下获得的MCNO薄膜在近红外波段表现出更强的吸收峰。射频溅射功率的改变会影响薄膜的厚度和结晶质量,从而对薄膜的光学带隙起到调控作用。光致发光光谱测试不同溅射功率下薄膜的缺陷峰发光强度,且在功率为80 W时沉积的薄膜具有最强紫外发射峰,表明改变溅射功率能够有效改善薄膜缺陷及提高晶体质量。